烷基羧酸钠的蠕虫状胶束流变性研究

J4 ›› 2010, Vol. 45 ›› Issue (1): 17-22.

烷基羧酸钠的蠕虫状胶束流变性研究

于丽孙焕泉肖建洪陈辉纪永强郑利强李干佐

于丽肖建洪陈辉：中国石化股份胜利油田分公司孤岛采油厂, 山东东营 257231;于丽纪永强郑利强李干佐：山东大学胶体与界面化学教育部重点实验室, 山东济南 250100;孙焕泉：中国石化股份胜利油田分公司, 山东东营 257000

收稿日期:2009-07-20 出版日期:2010-01-16 发布日期:2010-03-25
作者简介:于丽(1972-),女,博士,副教授，主要从事油田化学及表面活性剂物理化学研究. Email:ylmlt@sdu.edu.cn
基金资助:
国家“十一五”支撑计划资助项目(2007BAE52B052);中国博士后科学基金资助项目(20080441156);山东省科技攻关资助项目(2006GG2206004,2009GG10003027);山东省博士后创新专项基金资助项目(200701005)

Studies on rheological properties of wormlikemicelles formed by sodium carboxylate

Received:2009-07-20 Online:2010-01-16 Published:2010-03-25

摘要/Abstract

摘要：

针对油田开发实际,研究了温度、醇、烷烃、无机盐、油田水质矿化度、聚合物等因素对烷基羧酸钠——油酸钠(NaOA)在磷酸钠(Na₃PO₄)存在条件下形成的蠕虫状胶束流变性质的影响。不仅从理论上对蠕虫状胶束的零剪切粘度、剪切活化能等流变性质进行了分析和解释,而且为拓宽阴离子蠕虫状胶束在石油开采领域的应用提供了依据。

关键词: 蠕虫状胶束;流变性;油酸钠;磷酸钠

Abstract:

The effects of various factors on rheological properties of wormlike micelles formed by sodium carboxylate, namely sodium oleate (NaOA) aqueous solution in the presence of trisodium phosphate (Na₃PO₄) were investigated. These factors include temperature, alcohols, alkane, inorganic salts, the mineralization of oil field water and polymes, which are frequently encounteredin the oilfield development process. The rheological properties of wormlike micelles, such as zero shear viscosity and shear activation energy were analyzed and explained. These studies provide the basis of applications of wormlike micelles to oilfields.
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Key words: wormlike micelles; rheological properties; sodium oleate; trisodium phosphate

于丽孙焕泉肖建洪陈辉纪永强郑利强李干佐. 烷基羧酸钠的蠕虫状胶束流变性研究[J]. J4, 2010, 45(1): 17-22.

YU Li, SUN Huan-Quan, XIAO Jian-Hong, CHEN Hui, JI Yong-Qiang, ZHENG Li-Qiang, LI Gan-Zuo. Studies on rheological properties of wormlikemicelles formed by sodium carboxylate[J]. J4, 2010, 45(1): 17-22.

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