过渡金属和镧系金属卟啉配合物的合成与表征

过渡金属和镧系金属卟啉配合物的合成与表征

柳巍

山东理工大学材料科学与工程学院，山东淄博255049

收稿日期:2006-02-11 修回日期:1900-01-01 出版日期:2006-10-24 发布日期:2006-10-24
通讯作者: 柳巍

Synthesis and characterization of transition metal complexes and lanthanide porphyrin complex

LIU Wei

College of Materials Science and Engineering, Shandong University of Technology, Zibo 255049， Shandong, China

Received:2006-02-11 Revised:1900-01-01 Online:2006-10-24 Published:2006-10-24
Contact: LIU Wei

摘要/Abstract

摘要： 合成了新型5, 10, 15, 20-四(对-(4-氟苯甲酰氧基苯基))过渡金属卟啉和新型镧系乙酰丙酮-5, 10, 15, 20-四(对-(4-氟苯甲酰氧基苯基))卟啉配合物，并用元素分析，紫外可见光谱，红外光声光谱，摩尔电导，核磁共振氢谱以及X-射线光电子能谱对其组成和结构进行了表征.

关键词: 卟啉, 过渡金属配合物, 镧系金属配合物

Abstract: Transition metal complexes of 5, 10, 15, 20-tetra (para- (4-fliurobenzoyloxy) phenyl) porphyrin MTFBOPP (M=Mn, Fe, Co, Ni, Cu, Zn) and lanthanide complexes of acetylacetonate-5, 10, 15, 20-tetra (para- (4- fliurobenzoyloxy) phenyl) porphyrin LnTFBOPPacac (Ln=Sm, Gd, Tb, Lu) were synthesized and characterized by UV-Vis, IR photoacoustic,¹HNMR spectroscopy, elemental analyses, molar conductitvity and XPS.

Key words: lanthanide complex , transitional metal complex, porphyrin

中图分类号:

O611

柳巍 . 过渡金属和镧系金属卟啉配合物的合成与表征[J]. J4, 2007, 42(3): 60-63 .

LIU Wei . Synthesis and characterization of transition metal complexes and lanthanide porphyrin complex[J]. J4, 2007, 42(3): 60-63 .

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