聚苯胺/聚(苯乙烯-苯乙烯磺酸钠) 纳米核-壳结构聚合物的微乳液法合成及性能表征

聚苯胺/聚(苯乙烯-苯乙烯磺酸钠) 纳米核-壳结构聚合物的微乳液法合成及性能表征

姚慧玲¹，石元昌¹，翟光耀¹，张晓燕²

1 山东大学材料学院，山东济南 250061； 2 济南市科技信息研究所，山东济南 250001

收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2006-10-24 发布日期:2006-10-24
通讯作者: 姚慧玲

Preparation and characterization of PANI-coated poly (styrene co-styrene sulfonate) nanoparticles synthesized in a microemulsion system

YAO Hui-ling¹，SHI Yuan-chang¹，ZHAI Guang-yao ¹，ZHANG Xiao-yan²

1. School of Material Science and Engineering, Shandong University, Jinan 250061, Shandong; 2. Technology and Information Research Institute of Jinan, Jinan 250001, Shandong, China

Received:1900-01-01 Revised:1900-01-01 Online:2006-10-24 Published:2006-10-24
Contact: YAO Hui-ling

摘要/Abstract

摘要： 核壳结构的导电聚合物微粒以其优良的物理性质和化学性质，在能源、光电子、导电涂料等领域有广泛的应用前景。在微乳液体系中合成了核壳结构的聚苯胺/聚(苯乙烯-苯乙烯磺酸钠)微球。即首先在水包油（o/w）微乳液体系中制备苯乙烯和苯乙烯磺酸钠共聚物纳米微球，然后在低温下，使苯胺单体于共聚物纳米微球表面原位聚合制备核壳结构的纳米微球。

关键词: 微乳液, 聚苯胺, 核壳结构 , 聚苯胺/聚(苯乙烯-苯乙烯磺酸钠)纳米微球

Abstract: Core-shell structured nanoparticles of conducting polymers have outstanding physical and chemical property and broad application in many domains, such as energy, photoelectron and conducting dope. PANI-coated poly(styrene-co-styrene sulfonate) (PANI/PS-PSS) nanoparticles were prepared. First, nanoparticles of poly(styrene-co-styrene sulfonate)（PS-PSS）were synthesized in a nitrogen atmosphere by a microemulsion system, then the PS-PSS particles were used as templates to prepare PAIN-coated core-shell PANI/PS-PSS nanoparticles under a low temperature.

Key words: core-shell structure , polyaniline/poly(styrene-co-styrene sulfonate) nanoparticles, microemulsion

中图分类号:

姚慧玲,石元昌,翟光耀,张晓燕 . 聚苯胺/聚(苯乙烯-苯乙烯磺酸钠) 纳米核-壳结构聚合物的微乳液法合成及性能表征[J]. J4, 2008, 43(3): 26-29 .

YAO Hui-ling,SHI Yuan-chang,ZHAI Guang-yao ,ZHANG Xiao-yan . Preparation and characterization of PANI-coated poly (styrene co-styrene sulfonate) nanoparticles synthesized in a microemulsion system[J]. J4, 2008, 43(3): 26-29 .

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