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Study of UV-vis and fluorescence spectra properties of the porphyrin-liposome compound P-GlyL

ZHAO Xiao-jing, BAO Mi, JIN Li-ming, FAN Sheng-di   

  1. The Key Laboratory of the State Ethnic Affairs Commission-Ministry of Education,Department of Biochemical Engineering, Dalian Nationalities University, Dalian116605, Liaoning, China
  • Received:1900-01-01 Revised:1900-01-01 Online:2006-10-24 Published:2006-10-24
  • Contact: ZHAO Xiao-jing

Abstract: Using the bromopeptide BrC5Gly2C16 and 5,10, 15-triphenyl-20-polyhydroxyllphenylporphyrin(HPTPP) as the basic raw materials, the porphyrin-liposome compound P-GlyL was synthesized and characterized by elemental analysis, UV-vis spectra, IR spectra and 1H NMR spectra, which is available for a novel molecular device. The UV-vis spectra and fluorescence spectra of this compound in the Zn2+ solution with a variable concentration was studied. The results show that the emission peak at 650.0nm decreases, and two new emission peaks at 438nm and 595nm appear when the Zn2+ solution is added. The fluorescence intensity is enhanced with an increase of metal ion concentration, while the peaks at 349.0nm and 698.5nm have a small red-shift of 0.5nm with their intensities increasing.

Key words: molecular device , the fluorescence spectra, porphyrin-liposome compound

CLC Number: 

  • O614.24
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