JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE) ›› 2019, Vol. 54 ›› Issue (1): 19-25, 35.doi: 10.6040/j.issn.1671-9352.0.2018.361

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Ball-milled CaCO3 nanoparticles for removal of Pb2+ in solution

Zhen-yu FENG1(),He-chun JIANG2,*()   

  1. 1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China
    2. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong, China
  • Received:2018-07-03 Online:2019-01-20 Published:2019-01-23
  • Contact: He-chun JIANG E-mail:fengzhenyu@sdu.edu.cn;jianghechun@sdu.edu.cn
  • Supported by:
    山东省自然科学基金资助项目(ZR2017PB007);山东大学实验室建设与管理研究项目(sy20183201);山东大学实验室建设与管理研究项目(sy20183205);山东大学实验室建设与管理研究项目(sy20181202);山东省材料化学安全检测技术重点实验室开放课题(2018SDCLHX005)

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Abstract:

Nano-sized CaCO3 granules were prepared by ball milling to remove Pb2+ in solution. The results of X-ray diffraction (XRD) clearly indicated that the products after the sorption experiments were composed of CaCO3 and PbCO3. The analysis of selected area electron diffraction (SEAD), transmission electron microscopy (TEM) mapping and scanning electron microscopy (SEM) images demonstrated the generation of PbCO3 nanocrystals and the surface-adsorption of Pb2+ on the CaCO3 adsorbents. The sorption isotherms and kinetics were also considered. All of the results indicated that the main type of interaction between Pb2+ and the as-prepared CaCO3 is dissolution-precipitation accompanied by surface-adsorption.

Key words: calcium carbonate, nanomaterials, lead ion, sorption

CLC Number: 

  • O65

Fig.1

Morphology and structure characterization of CaCO3 before and after ball milling"

Fig.2

Sorption kinetics of nano-sized CaCO3 and micro-sized CaCO3"

Table 1

Sorption kinetics data"

吸附剂 Qe/(mmol·g-1) k2/(g·mmol-1·h-1) R2
纳米级CaCO3 1.902 1.008 0.968
微米级CaCO3 1.893 0.3082 0.851

Fig.3

Sorption isotherms of nano-sized CaCO3 andmicro-sized CaCO3 at 30 ℃"

Table 2

Sorption isotherms data"

吸附剂 T/K Kf/((mmol/g)·(L/mmol)1/n) 1/n R2
纳米级CaCO3 303 5.54 0.060 8 0.996
微米级CaCO3 303 4.93 0.173 0 0.980

Fig.4

Morphology and structure characterization of nano-sized CaCO3 after adsorption test"

Table 3

Difference between metal ion concentrations in initial and equilibrium solutions"

金属离子 Ce-C0/(mmol·L-1)
试样1 试样2 试样3 试样4 试样5
Pb2+ -0.48 -0.82 -0.91 -0.95 -0.95
Ca2+ 0.36 0.63 0.73 0.72 0.75

Fig.5

Electron microscopy and elemental analysis of adsorbent after adsorption experiments"

Fig.6

Dosage of adsorbents used in sorption experiments"

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