J4 ›› 2008, Vol. 43 ›› Issue (5): 24-26 .doi:
• Articles • Previous Articles Next Articles
WANG Min-jie, ZHU Lian-xuan*, LIN Ai-ying
Received:
Revised:
Online:
Published:
Contact:
Abstract:
According to the semi-SCF d-orbit radial function, the point-charge model and the third-order perturbation formulae, the g-factors(g=1.9707) and the zero-field splitting D(D=-0.0323) were calculated, and the calculated results are in good agreement with the experimental results(experimental values g=1.976±0.001, D=-0.032?5±0.0001). The bond length R=(Cr3+—O2+)=0.191nm is rational. The angle increases a little (the increment 0.35°) after the Cr3+ replace the Al3+in AlBr3·6H2O crystals.
Key words: AlBr3·6H2O:Cr3+; spin-orbit coupling; electron paramagnetic resonance(EPR); crystal field structure
CLC Number:
WANG Min-jie,ZHU Lian-xuan*,LIN Ai-ying . Theoretical study of electron paramagnetic resonance of Cr3+ ions in AlBr3·6H2O crystals[J].J4, 2008, 43(5): 24-26 .
0 / / Recommend
Add to citation manager EndNote|Reference Manager|ProCite|BibTeX|RefWorks
URL: http://lxbwk.njournal.sdu.edu.cn/EN/
http://lxbwk.njournal.sdu.edu.cn/EN/Y2008/V43/I5/24
Cited
