仿刺参加工废液中几种海参皂苷化合物的分离鉴定

J4 ›› 2011, Vol. 46 ›› Issue (7): 17-20.

仿刺参加工废液中几种海参皂苷化合物的分离鉴定

袁文鹏¹,刘新¹,樊廷俊²,张永刚¹,夏雪奎¹,刘昌衡¹*

1. 山东省科学院生物研究所, 山东省应用微生物重点实验室, 山东济南 250014;
2. 中国海洋大学生命学院海洋生物系, 山东青岛 266003

收稿日期:2010-11-23 出版日期:2011-07-20 发布日期:2011-09-08
通讯作者: 刘昌衡(1962- ), 男, 研究员, 现主要进行海洋功能食品的研究. Email:liuchh@keylab.net
作者简介:袁文鹏(1979- ), 男, 理学博士, 助理研究员, 主要进行海洋功能食品及海洋天然产物的研究. Email:ouwenpengyuan@hotmail.com
基金资助:
山东省科学院科技发展基金资助项目(科基合字2007第14号);国家自然科学基金青年科学基金资助项目(31000008)

AIsolation and structure identification of several holothurian glycosides compounds from the processing liquid waste of sea cucumber Apostichopus japonicus

YUAN Wen-peng¹, LIU Xin¹, FAN Ting-jun², ZHANG Yong-gang¹, XIA Xue-kui¹, LIU Chang-heng¹*

1. Biology Institute of Shandong Academy of Sciences, Key Laboratory For Applied Microbiology of Shandong Province,
Jinan 250014, Shandong, China; 2. Department of Marine Biology, College of Marine Life Sciences,
Ocean University of China, Qingdao 266003, Shandong, China

Received:2010-11-23 Online:2011-07-20 Published:2011-09-08

摘要/Abstract

摘要：

为高值化利用海参加工废弃液资源,对废弃液中皂苷类化学成分进行了研究。运用大孔吸附树脂层析、硅胶柱层析、制备高效液相色谱等技术从仿刺参加工废液中分离得到5个海参皂苷类化合物,采用现代波谱技术(MS, NMR等)并与文献报道数据进行比较分别鉴定为:holotoxin D (1)、holotoxin B1(2)、holotoxin A (3)、holotoxin A1(4)、cladoloside B (5)。这些化合物均系首次从仿刺参加工废液资源中分离得到,为海参加工废液的合理开发与利用奠定基础。

关键词: 仿刺参;海参加工废液;海参皂苷

Abstract:

In order to explore higher applicative value of processing liquid waste of sea cucumber, holothurian glycosides compounds from the processing liquid waste of sea cucumber Apostichopus japonicus were investigated. The processing liquid waste was separated by macroporous resin chromatography, silica gel column chromatography and preparative high performance liquid chromatography to afford five compounds. On the basis of detailed spectroscopic analysis and comparison of the reported data in the literatures, they were elucidated as holotoxin D (1)、holotoxin B1(2)、holotoxin A (3)、holotoxin A1(4) and cladoloside B (5). All of the compounds were isolated from the Apostichopus japonicus processing liquid waste for the first time. This study laid a foundation for rational utilization and development of processing liquid waste of sea cucumber.

Key words: Apostichopus japonicus; processing liquid waste of sea cucumber; holothurian glycosides

袁文鹏1,刘新1,樊廷俊2,张永刚1,夏雪奎1,刘昌衡1*. 仿刺参加工废液中几种海参皂苷化合物的分离鉴定[J]. J4, 2011, 46(7): 17-20.

YUAN Wenpeng1, LIU Xin1, FAN Tingjun2, ZHANG Yonggang1, XIA Xuekui1, LIU Changheng1*. AIsolation and structure identification of several holothurian glycosides compounds from the processing liquid waste of sea cucumber Apostichopus japonicus[J]. J4, 2011, 46(7): 17-20.

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