您的位置：山东大学 -> 科技期刊社 -> 《山东大学学报（理学版）》

J4 ›› 2012, Vol. 47 ›› Issue (1): 23-27.

• 化学与环境 • 上一篇    下一篇

层状杂化材料M2(OH)(4-x) (C10H17O2)x·zH2O中有机官能团与无机金属的配位模式

郑德山1,2, 孙思修2   

  1. 1. 西安工业大学材料与化工学院, 陕西 西安 710032;  2. 山东大学化学与化工学院,山东 济南 250100
  • 收稿日期:2011-06-17 出版日期:2012-01-20 发布日期:2012-06-29
  • 作者简介:郑德山(1971- ),男,博士,研究方向为无机材料.Email: deshan.zheng@sdu.edu.cn
  • 基金资助:

    西安工业大学校长基金资助项目(XAGDXJJ1009)

The coordination mode between organic functional groups and inorganic metal of layered hybrid materials M2(OH) (4-x) (C10H17O2)x·zH2O

ZHENG De-shan1, 2, SUN Si-xiu2   

  1. 1. School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710032, Shaanxi, China;
    2. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China
  • Received:2011-06-17 Online:2012-01-20 Published:2012-06-29

PDF (PC)

1560

摘要：

 运用红外光谱(IR)技术对嫁接了手性3,7-二甲基-6-辛烯酸的杂化材料M2(OH) (4-x) (C10H17O2)x·zH2O中有机官能团与无机金属的配位模式进行了分析和讨论。结果表明,有机-无机杂化材料M2(OH) (4-x) (C10H17O2)x·zH2O中,羧基官能团采取了二齿配位的连接方式,一端与无机金属连接,另一端通过氢键与羟基或者水键合。

关键词: 层状化合物;杂化材料;配位模式

Abstract:

The coordination mode between organic functional groups and inorganic metal of layered hybrid materials M2(OH) (4-x) (C10H17O2)x·zH2O, synthesized by grafting of chiral 3,7-dimethyl-6-Octenoic acid in layered hydroxide metal acetates, was analyzed and discussed using infrared spectroscopy (IR) technology. The results showed that the carboxyl functional groups in the organic-inorganic hybrid material M2(OH) (4-x) (C10H17O2)x·zH2O took a bidentate coordination mode, one end of the carboxyl functional groups connected to the inorganic metal ion, the other one end of it bonded the hydroxyl or water by hydrogen bonds.
 

Key words: layered compound; hybrid material; coordination mode

No related articles found!
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
版权所有 © 2018 《山东大学学报(理学版)》编辑部　
地址: 山东省济南市山大南路27号山东大学中心校区（250100）　电话: +86-0531-88366917　E-mail: xblxb@sdu.edu.cn
本系统由北京玛格泰克科技发展有限公司设计开发