JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE) ›› 2018, Vol. 53 ›› Issue (3): 88-94.doi: 10.6040/j.issn.1671-9352.0.2017.377

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Catalytic amination of sym-triazinetriol with diethylenetriamine

MENG Li1, WANG Qian2, CHAI Shu1, ZHU Wei-qun1*   

  1. 1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China;
    2. Institute of National Engineering Research Center for Colloidal Materials, Shandong University, Jinan 250100, Shandong, China
  • Received:2017-07-31 Online:2018-03-20 Published:2018-03-13

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Abstract: As a carbon resource, it has become one of the hot spots at present through the chemical utilization of CO2 to achieve emission reduction purposes. Sym-triazinetriol is kind of CO2 sequestration products, and it has broad prospects to develop its downstream products. In this paper, synthesis of 6-divinyl three amine-1,3,5-triazine base-2,4(1H,3H)-diketone by diethylenetriamine(DETA)and Sym-triazinetriol(CA)was studied. The effects of molar ratio, reaction time, reaction temperature and catalyst on the yields were investigated by single-factor method. Then, the product was characterized by IR, 1H NMR and 13C NMR. The optimum conditions were as follows: the molar ratio of CA to DETA was 1∶4, the reaction temperature was 210 ℃, the reaction time was 4 h, the catalyst was 5A molecular sieve. The yield of product can reach 70.9%.

Key words: sym-triazinetriol, diethylenetriamine, synthesis, carbon sequestration product

CLC Number: 

  • TQ9
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