ZnO/SnO复合纳米棒的水热合成及气敏研究

doi:10.6040/j.issn.1671-9352.0.2014.194

山东大学学报（理学版） ›› 2014, Vol. 49 ›› Issue (07): 18-22.doi: 10.6040/j.issn.1671-9352.0.2014.194

ZnO/SnO复合纳米棒的水热合成及气敏研究

封振宇¹, 包文亚¹, 张诗舒¹, 张俊彦¹, 张正林²

1. 山东大学化学与化工学院, 山东济南 250100;
2. 哈尔滨师范大学化学化工学院, 黑龙江哈尔滨 150025

收稿日期:2014-05-04 出版日期:2014-07-20 发布日期:2014-09-15
作者简介:封振宇（1983- ），男，助理工程师，硕士，研究方向为无机材料化学.E-mail：fengzhenyu@sdu.edu.cn

Hydrothermal synthesis of ZnO/SnO composite nanorods as gas sensors for volatile organic compounds detection

FENG Zhen-yu¹, BAO Wen-ya¹, ZHANG Shi-shu¹, ZHANG Jun-yan¹, ZHANG Zheng-lin²

1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China;
2. School of Chemistry and Chemical Engineering, Harbin normal university, Harbin 150025, Heilongjiang, China

Received:2014-05-04 Online:2014-07-20 Published:2014-09-15

摘要/Abstract

摘要： 运用水热法合成六方纤锌矿ZnO纳米棒，在ZnO纳米棒表面水热生长SnO，获得了表面疏松的ZnO/SnO复合纳米棒材料。运用X射线粉末衍射（XRD）、透射电子显微镜（TEM）、扫描电子显微镜（SEM）、电子能谱（EDS）等手段表征了该材料的形貌和组成。BET氮吸附测试表明其表面疏松结构具有11.38 m²/g的比表面积。气敏实验证明了该材料对甲醛气体具有百万分率浓度级检测灵敏度，对于开发甲醛传感材料具有理论意义和潜在应用价值。

关键词: 气敏, 复合纳米棒, SnO, ZnO

Abstract: The Porous ZnO/SnO composite nanorods were fabricated through hydrothermal method. The prepared hexagonal wurtzite structure ZnO nanorods were coated by SnO as porous shells. The structure and morphology of the resultant products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive spectrdmeter (EDS). The BET nitrogen adsorption—desorption technique indicated the as-prepared composite nanorods with 11.38 m²/g surface area. The gas sensing properties of the as-prepared ZnO/SnO composite nanorods were investigated. The composite nanorods exhibited a superior gas sensing performance toward ppm level formaldehyde vapor, implying promising applications in detecting toxic volatile organic compounds (VOCs).

Key words: SnO, gas sensor, composite nanorod, ZnO

中图分类号:

O614

封振宇, 包文亚, 张诗舒, 张俊彦, 张正林. ZnO/SnO复合纳米棒的水热合成及气敏研究[J]. 山东大学学报（理学版）, 2014, 49(07): 18-22.

FENG Zhen-yu, BAO Wen-ya, ZHANG Shi-shu, ZHANG Jun-yan, ZHANG Zheng-lin. Hydrothermal synthesis of ZnO/SnO composite nanorods as gas sensors for volatile organic compounds detection[J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2014, 49(07): 18-22.

参考文献

[1] OZGUR U, ALIVOV Ya I, LIU C, et al. A comprehensive review of ZnO materials and devices[J]. Journal of Applied Physics, 2005, 98:041301.
[2] LUKAS Schmidt-Mende, JUDITH L, MAC Manus-Driscoll. ZnO-nanostructures, defects, and devices[J]. Materials Today, 2007, 10(5):40-48.
[3] JING Zhihong, ZHAN Jinhua. Fabrication and Gas-Sensing Properties of Porous ZnO Nanoplates[J]. Advanced Materials, 2008, 20:4547-4551.
[4] SONG Haiyan, YANG Heng, MA Xicheng. A comparative study of porous ZnO nanostructures synthesized from different zinc salts as gas sensor materials[J]. Journal of Alloys and Compounds, 2013, 578:272-278.
[5] LI Zhipeng, PAN Wenxiao, ZHANG Dongju, et al. Morphology-Dependent Gas-Sensing Properties of ZnO Nanostructures for Chlorophenol[J]. Chemistry an Asian Journal, 2010, 5:1854-1859.
[6] LIU Xianghong, ZHANG Jun, WANG Liwei, et al. 3D hierarchically porous ZnO structures and their functionalization by Au nanoparticles for gas sensors[J]. Journal of Materials Chemistry, 2011, 21:349-356.
[7] ZHU Guoxing, XU Huan, LIU Yuanjun, et al. Enhanced gas sensing performance of Co-doped ZnO hierarchical microspheres to 1,2-dichloroethane[J]. Sensors and Actuators B:Chemical, 2012, 166-167:36-43.
[8] LIU Li, LI Shouchun, ZHUANG Juan, et al. Improved selective acetone sensing properties of Co-doped ZnO nanofibers by electrospinning[J]. Sensors and Actuators B:Chemical, 2011, 155:782-788.
[9] YU Ang, QIAN Jieshu, PAN Hao, et al. Micro-lotus constructed by Fe-doped ZnO hierarchically porous nanosheets:Preparation, characterization and gas sensing property[J]. Sensors and Actuators B:Chemical, 2011, 158:9-16.
[10] LI Zhipeng, ZHAO Quanqin, FAN Weiliu, et al. Porous SnO₂ nanospheres as sensitive gas sensors for volatile organic compounds detection [J]. Nanoscale, 2011, 3:1646-1652.
[11] ZHANG Zhenglin, SONG Haiyan, ZHANG Shishu, et al. Selective epichlorohydrin-sensing performance of Ag nanoparticles decorated porous SnO₂ architectures [J]. Cryst Eng Comm, 2014, 16:110-115.
[12] WANG Weiwei, ZHU Yingjie, YANG Lixia. ZnO-SnO₂ Hollow Spheres and Hierarchical Nanosheets:Hydrothermal Preparation, Formation Mechanism, and Photocatalytic Properties [J]. Advanced Functional Materials, 2007, 17:59-64.
[13] Nguyen Duc Khoang, Do Dang Trung, Nguyen Van Duy, et al. Design of SnO₂/ZnO hierarchical nanostructures for enhanced ethanol gas-sensing performance [J]. Sensors and Actuators B:Chemical, 2012, 174:594-601.
[14] MA Xicheng, SONG Haiyan, GUAN Congsheng. Enhanced ethanol sensing properties of ZnO-doped porous SnO₂ hollow nanospheres [J]. Sensors and Actuators B:Chemical, 2013, 188:193-199.
[15] TIAN Shouqin, GAO Yingri, ZENG Dawen, et al. Effect of Zinc Doping on Microstructures and Gas-Sensing Properties of SnO₂ Nanocrystals [J]. Journal of the American Ceramic Society, 2012, 95(1):436-442.
[16] WANG Wenchuang, TIAN Yongtao, LI Xinjian, et al. Enhanced ethanol sensing properties of Zn-doped SnO₂ porous hollow microspheres [J]. Applied Surface Science, 2012, 261:890-895.
[17] CHOPRA K L, MAJOR S, PANDYA D K. Transparent conductors-A status review [J]. Thin Solid Films, 1983, 102(1):1-46.
[18] WATSON J. The tin oxide gas sensor and its applications [J]. Sensors and Actuators, 1984, 5(1):29-42.
[19] SEIYAMA T, KATO A, FUJIISHI K, et al. A new detector for gaseous components using semiconductive thin films [J]. Analytical Chemistry, 1962, 34(11):1502-1503.
[20] YAMAZOE N, SAKAI G, SHIMANOE K. Oxide semiconductor gas sensors [J]. Catalysis Surveys from Asia, 2003, 7(1):63-75.

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ZnO/SnO复合纳米棒的水热合成及气敏研究

Hydrothermal synthesis of ZnO/SnO composite nanorods as gas sensors for volatile organic compounds detection

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