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《山东大学学报(理学版)》 ›› 2021, Vol. 56 ›› Issue (10): 99-112.doi: 10.6040/j.issn.1671-9352.9.2021.005

• • 上一篇    

聚硅氧烷基荧光材料

冯圣玉,谌梓煦,王灯旭*   

  1. 山东大学化学与化工学院, 特种功能聚集体材料教育部重点实验室, 国家胶体材料工程技术研究中心, 山东 济南 250100
  • 发布日期:2021-09-28
  • 作者简介:冯圣玉(1958— ),男,博士,教授,博士生导师,研究方向为有机硅高分子. E-mail:fsy@sdu.edu.cn*通信作者. E-mail:dxwang@sdu.edu.cn
  • 基金资助:
    国家自然科学基金资助项目(21774070);山东省自然科学基金资助项目(ZR2019MB028)

Polysiloxane-based fluorescent materials

FENG Sheng-yu, CHEN Zi-xu, WANG Deng-xu*,   

  1. Key Laboratory of Special Functional Aggregated Materials, Ministry of Education;
    National Engineering, Research Center for Colloidal Materials;
    School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China
  • Published:2021-09-28

摘要: 聚硅氧烷基荧光材料作为一类性能独特的有机硅材料,在荧光探针、生物传感、力学传感、发光二极管等领域具有广阔的应用前景。基于近十几年来国内外聚硅氧烷基荧光材料的相关报道,文中结合本课题组的研究成果,综述了线型、超支化和交联3类结构的聚硅氧烷基荧光材料的研究进展,总结了各类荧光材料的合成、应用及发光机理,探讨了聚硅氧烷在荧光材料中的作用,并对未来聚硅氧烷基荧光材料的发展方向进行了总结和展望。

关键词: 聚硅氧烷, 荧光材料, 超支化聚硅氧烷, 硅橡胶, 有机硅

Abstract: Polysiloxane-based fluorescent materials as a class of organosilicon materials with unique properties have found extensive applications, including fluorescent probes, biosensing, mechanical sensing, and light-emitting diodes. In this review, based on the literatures on polysiloxane-based fluorescent materials at home and abroad and the results from our group in recent decades, the progress in three types of polysiloxane-based fluorescent materials, including linear, hyperbranched, and crosslinked structures, are summarized from the viewpoints of synthesis, applications, and fluorescent mechanism. In particular, the function of polysiloxanes in these fluorescent materials is discussed. Finally, the trend and prospects of polysiloxane-based fluorescent materials are presented.

Key words: polysiloxane, fluorescent material, hyperbranched polysiloxane, silicone rubber, organosilicon

中图分类号: 

  • O648
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