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山东大学学报（理学版） ›› 2018, Vol. 53 ›› Issue (3): 88-94.doi: 10.6040/j.issn.1671-9352.0.2017.377

• • 上一篇    

1,3,5-均三嗪三醇与二乙烯三胺的催化胺化反应

孟丽1,王倩2,柴树1,朱维群1*   

  1. 1.山东大学化学与化工学院, 山东 济南 250100;2.山东大学国家胶体材料工程技术研究中心, 山东 济南 250100
  • 收稿日期:2017-07-31 出版日期:2018-03-20 发布日期:2018-03-13
  • 通讯作者: 朱维群(1961— ),男,教授,硕士生导师,研究方向为CO2封存利用及脱硫脱硝理论和技术开发应用研究.E-mail:zhuwq@sdu.edu.cn E-mail:mengli0621@163.com
  • 作者简介:孟丽(1992— ),女,硕士,研究方向为CO2封存利用及1,3,5-均三嗪三醇的应用研究.E-mail:mengli0621@163.com
  • 基金资助:
    山东省重点研发计划资助项目(2017CXGC1008)

Catalytic amination of sym-triazinetriol with diethylenetriamine

MENG Li1, WANG Qian2, CHAI Shu1, ZHU Wei-qun1*   

  1. 1. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China;
    2. Institute of National Engineering Research Center for Colloidal Materials, Shandong University, Jinan 250100, Shandong, China
  • Received:2017-07-31 Online:2018-03-20 Published:2018-03-13

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摘要： CO2作为一种碳资源,对其进行化学利用以达到减排目的,已成为目前科学研究热点之一。1,3,5-均三嗪三醇是一种CO2封存产品,开发其下游产品具有广阔前景。以1,3,5-均三嗪三醇(sym-triazinetriol, CA)与二乙烯三胺(diethylenetriamine, DETA)为原料,合成6-二乙烯三胺基-1,3,5-三嗪-2,4(1H,3H)-二酮。采用单因素法探讨了反应物摩尔比、反应时间、反应温度以及催化剂对产率的影响,由FT-IR、1H NMR与13C NMR等表征产物。反应最佳条件:CA与DETA摩尔比为1∶4,反应温度210 ℃,反应时间为4 h,催化剂为5A分子筛,产率为70.9%。

关键词: 固碳产品, 1,3,5-均三嗪三醇, 二乙烯三胺, 合成

Abstract: As a carbon resource, it has become one of the hot spots at present through the chemical utilization of CO2 to achieve emission reduction purposes. Sym-triazinetriol is kind of CO2 sequestration products, and it has broad prospects to develop its downstream products. In this paper, synthesis of 6-divinyl three amine-1,3,5-triazine base-2,4(1H,3H)-diketone by diethylenetriamine(DETA)and Sym-triazinetriol(CA)was studied. The effects of molar ratio, reaction time, reaction temperature and catalyst on the yields were investigated by single-factor method. Then, the product was characterized by IR, 1H NMR and 13C NMR. The optimum conditions were as follows: the molar ratio of CA to DETA was 1∶4, the reaction temperature was 210 ℃, the reaction time was 4 h, the catalyst was 5A molecular sieve. The yield of product can reach 70.9%.

Key words: sym-triazinetriol, diethylenetriamine, synthesis, carbon sequestration product

中图分类号: 

  • TQ9
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