JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE) ›› 2016, Vol. 51 ›› Issue (11): 88-92.doi: 10.6040/j.issn.1671-9352.0.2016.366

Previous Articles     Next Articles

Synthesis of sulphur-functionalized disiloxanes by thiol-ene “click”reaction and their luminescent properties

ZUO Yu-jing, FENG Sheng-yu*   

  1. Key Laboratory of Special Functional Aggregated Materials of Ministry of Education;
    School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China
  • Received:2016-07-28 Online:2016-11-20 Published:2016-11-22

PDF (PC)

666

Abstract: Using divinyltetramethyldisiloxane(MMVi)as the starting materials, a series of functionalized disiloxanes(S1-S4)have been synthesized between MMVi and four types of thiols(propanethiol, mercaptoacetic acid, thiohydracrylic acid, and methyl 3-mercaptopropionate)via facile thiol-ene “click” reaction and characterized by NMR(1H, 13C)and mass spectroscopy. Their luminescent properties were characterized by Fluorescence Spectrometer and show strong and narrow emission peak, which means these compounds could be applied in optical devices.

Key words: thiol-ene “click” reaction, sulphur-functionalized disiloxanes, luminescent properties

CLC Number: 

  • O211
[1] 冯圣玉, 张洁, 李美江, 等.有机硅高分子及其应用[M].北京: 化学工业出版社, 2004:34-71.
[2] 周振宇, 王政, 顾晓丹, 等.几种含α-官能团的二硅氧烷的合成与表征[J]. 有机硅材料, 2009, 23(5):288-292.
[3] ZHANG T, LITT M H, ROGERS C E. Sulfone-containing polymers as high barrier materials[J].J Polym Sci, Part B: Polym Phys, 1994, 32(9):1671-1676.
[4] TITVINIDZE G, KREUER K D, SCHUSTER M, et al. Proton conducting phase-separated multiblock copolymers with sulfonated poly(phenylene sulfone)blocks for electrochemical applications:Preparation, Morphology, Hydration behavior, and Transport[J].Adv Funct Mater, 2012, 22(21):4456-4470.
[5] TUCKER-SCHWARTZ A K, FARRELL R A, GARRELL R L. Thiol—ene click reaction as a general route to functional trialkoxysilanes for surface coating applications [J]. J Am Chem Soc, 2011, 133(29):11026-11029.
[6] CAMPOS L M, MEINEL I, GUINO R G, et al.Highly versatile and robust materials for soft imprint lithography based on thiol-ene click chemistry[J]. Adv Mater, 2008, 20(19):3728-3733.
[7] DESROCHES M, CAILLOL S, LAPINTE V, et al.Synthesis of biobased polyols by thiol-ene coupling from vegetable oils[J].Macromolecules, 2011, 44(8):2489-2500.
[8] HOYLE C E, BOWMAN C N.Thiol—Ene click chemistry[J].Angew Chem Int Ed, 2010, 49(9):1540-1573.
[9] CAMPOS L M, TRUONG T T, SHIM D E, et al.Applications of photocurable PMMS thiol-ene stamps in soft lithography[J]. Chem Mater, 2009, 21(21):5319-5326.
[10] LLUCH C, RONDA J C, GALIÀ M, at al.Rapid approach to biobased telechelics through two one-pot thiol-ene click reactions[J]. Biomacromolecules, 2010, 11(6):1646-1653.
[11] ZUO Y, WANG D, FENG S, et al. Multifunctional alkoxysilanes prepared by thiol—yne “click” chemistry:their luminescenceproperties and modification on a silicon surface[J].RSC Adv, 2014, 4(108):62827-62834.
[12] XUE L, WANG D, FENG S, et al. Facile, versatile and efficient synthesis of functional polysiloxanes via thiol—ene chemistry[J]. Eur Polym J, 2013, 49:1050-1056.
[13] RISSING C, SON D Y. Thiol-ene reaction for the synthesis of multifunctional branched organosilanes[J]. Organometallics, 2008, 27(20):5394-5397.
[14] ZUO Y, GOU Z, FENG S, et al. From polymer to monomer:cleavage and rearrangement ofSi-O-Si bonds after oxidation yielded an ordered cycliccrystallized structure[J]. Chem-Eur J, 2015, 21(31):10972-10977.
[15] WANG X, XU L, FENG S, et al. Silicon effect of dendritic polyphenyl derivatives:enhancement of aggregation-induced emissionand emission color adjustment[J]. RSC Adv, 2016, 6(28):23335-23339.
[16] WANG D, WANG L, FENG S, et al. Tetrahedral silicon-based luminescent molecules: synthesis and comparison of thermal and photophysical properties by various effect factors[J].J Organomet Chem, 2013, 735:58-64.
[17] KULKARNI A P, TONZOLA C J, BABEL A, et al. Electron transport materials for organic light-emitting diodes[J].Chem Mater, 2004, 16(23):4556-4573.
[1] MA Ming, BIAN Li-na, LIU Hua. Low order moments of self-excited filtered Poisson processes based on joint distribution of event points [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2018, 53(4): 55-58.
[2] XIAO Xin-ling. Forward-backward stochastic differential equations on Markov chains [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2018, 53(4): 46-54.
[3] CHEN Li, LIN Ling. Stock option pricing with time delay [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2018, 53(4): 36-41.
[4] ZHANG Ya-juan, LYU Yan. Approximation of stochastic vibration equations with variable damping [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2018, 53(4): 59-65.
[5] LI Xiao-juan, GAO Qiang. Regularity for product space under sublinear expectation framework [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2018, 53(4): 66-75.
[6] HUANG Ai-ling, LIN Shuai. Finite dimensional approximation of linear stochastic Schrödinger equation in terms of localization of quantum Bernoulli noises [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(12): 67-71.
[7] CUI Jing, LIANG Qiu-ju. Existence and controllability of nonlocal stochastcic integro-differential equations driven by fractional Brownian motion [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(12): 81-88.
[8] RONG Wen-ping, CUI Jing. μ-pseudo almost automorphic solutions for a class of stochastic evolution equations under non-Lipschitz conditions [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(10): 64-71.
[9] FENG De-cheng, ZHANG Xiao, ZHOU Lin. A class of minimal inequalities for demimartingales [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(8): 65-69.
[10] ZHANG Jie-song. Diffusion approximation and optimal investment for modern risk model [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(5): 49-57.
[11] YANG Xu, LI Shuo. Comparison theorem for backward doubly stochastic differential equations driven by white noises and Poisson random measures [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(4): 26-29.
[12] ZHANG Ya-yun, WU Qun-ying. Precise asymptotics in the law of iterated logarithm for the moment convergence of ρ-mixing sequences [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(4): 13-20.
[13] FENG De-cheng, WANG Xiao-yan, GAO Yu-feng. Maximal φ-inequalities for conditional N-demimartingales based on Y functions [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(2): 91-96.
[14] ZHANG Tao, LI Xiao-lin, CHEN Ping-yan. Strong laws for extreme values from a class of Gaussian sequences [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(2): 97-100.
[15] DENG Xiao-qin, WU Qun-ying. Precise asymptotics in the complete moment convergence for NA random variables [J]. JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE), 2017, 52(1): 102-110.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
Copyright 2018 © Editorial office of JOURNAL OF SHANDONG UNIVERSITY(NATURAL SCIENCE)
Supported by Beijing Magtech Co.Ltd