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山东大学学报（理学版） ›› 2016, Vol. 51 ›› Issue (11): 88-92.doi: 10.6040/j.issn.1671-9352.0.2016.366

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经巯-烯反应合成含硫官能基二硅氧烷及其荧光性能研究

左育静,冯圣玉*   

  1. 山东大学化学与化工学院特种功能聚集体材料教育部重点实验室, 山东 济南 250100
  • 收稿日期:2016-07-28 出版日期:2016-11-20 发布日期:2016-11-22
  • 通讯作者: 冯圣玉(1958— ),男,教授,博士生导师,研究方向为有机硅化学和有机硅高分子材料的研究.E-mail:fsy@sdu.edu.cn E-mail:zuoyujing0888@163.com
  • 作者简介:左育静(1990— ),女,博士研究生,研究方向为有机硅化学和有机硅高分子材料的研究.E-mail:zuoyujing0888@163.com
  • 基金资助:
    国家自然科学基金资助项目(21274080);山东省自主创新基金资助项目(2014ZZCXO1101)

Synthesis of sulphur-functionalized disiloxanes by thiol-ene “click”reaction and their luminescent properties

ZUO Yu-jing, FENG Sheng-yu*   

  1. Key Laboratory of Special Functional Aggregated Materials of Ministry of Education;
    School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China
  • Received:2016-07-28 Online:2016-11-20 Published:2016-11-22

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摘要： 以1,1,3,3-四甲基-1,3-二乙烯基二硅氧烷为起始原料,分别与1-丙硫醇、硫代乙醇酸、巯基丙酸、巯基丙酸甲酯进行巯-烯“点击”反应,制备了4种含硫官能基二硅氧烷:1,1,3,3-四甲基-1,3-双(2-(丙硫基)乙基)二硅氧烷、3,3'-(1,1,3,3-四甲基二硅氧烷-1,3-二乙基硫醚基)双乙酸、3,3'-(1,1,3,3-四甲基二硅氧烷-1,3-二乙基硫醚基)双丙酸、3,3'-(1,1,3,3-四甲基二硅氧烷-1,3-二乙基硫醚基)双丙酸甲酯。采用IR、NMR、GC-MS等方法对产物结构进行了表征。研究结果发现,合成的化合物在紫外-蓝光区有着强而窄的荧光发射,使得它们在光学器件方面有潜在的应用价值。

关键词: 巯-烯反应, 荧光性能, 含硫官能基二硅氧烷

Abstract: Using divinyltetramethyldisiloxane(MMVi)as the starting materials, a series of functionalized disiloxanes(S1-S4)have been synthesized between MMVi and four types of thiols(propanethiol, mercaptoacetic acid, thiohydracrylic acid, and methyl 3-mercaptopropionate)via facile thiol-ene “click” reaction and characterized by NMR(1H, 13C)and mass spectroscopy. Their luminescent properties were characterized by Fluorescence Spectrometer and show strong and narrow emission peak, which means these compounds could be applied in optical devices.

Key words: thiol-ene “click” reaction, sulphur-functionalized disiloxanes, luminescent properties

中图分类号: 

  • O211
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